MEASURAND : Amount content of Cadmium in natural water
NOMINAL VALUE : 83 nmol/kg

Degrees of equivalence Di and expanded uncertainty Ui (k = 2) expressed in nmol/kg

MEASURAND : Amount content of Lead in natural water
NOMINAL VALUE : 63 nmol/kg

Degrees of equivalence Di and expanded uncertainty Ui (k = 2) expressed in nmol/kg

MEASURAND : Amount content of Cadmium in natural water
NOMINAL VALUE : 83 nmol/kg

   
Lab iDiUi
 /(nmol/kg)/(nmol/kg)
IRMM-0.13.0
KRISS-0.62.1
LGC-0.41.8
LNE1.34.2
NIMC1.12.6
NIST-1.11.7
NMi0.42.5
NRC0.22.8
PTB-0.82.8

The full matrix of equivalence is available in Summary Results (summary of the results as a .PDF file).

MEASURAND : Amount content of Lead in natural water
NOMINAL VALUE : 63 nmol/kg

   
Lab iDiUi
 /(nmol/kg)/(nmol/kg)
IRMM-0.12.7
KRISS-0.52.8
LGC-0.42.9
LNE3.13.8
NIMC-0.62.7
NIST0.12.7
NMi-1.43.5
NRC-0.23.1
PTB-1.82.8

The full matrix of equivalence is available in Summary Results (summary of the results as a .PDF file).

Comparison
Comparison close
CC comparison
Linked comparison
CCQM-K2
Metrology area, Sub-field Chemistry and Biology, Inorganics
Description Cadmium and Lead in natural water
Time of measurements 1998
Status Approved for equivalence
Final Reports of the comparisons
Measurand Amount content of Cadmium (Cd): 83 nmol/kg and Lead (Pb) : 63 nmol/kg
Transfer device Sample from International Measurement Evaluation Programme: IMEP-9
Comparison type Key Comparison
Consultative Committee CCQM (Consultative Committee for Amount of Substance)
Conducted by CCQM (Consultative Committee for Amount of Substance)
Comments

Results published in October 2000

Cadmium and Lead in natural water

Pilot institute IGM
Inspection Générale de la Métrologie
Belgium
Contact person I. Papadakis

+32 (0) 14 571 682
First Name Last Name
wwww@ww.www +356719836 Institute 1 Institute 1 Khmelnitskiy
BNM-LNE

Bureau National de Métrologie - Laboratoire National d'Essais, France, EURAMET

IRMM

Institute for Reference Materials and Measurements, European Union, EURAMET

KRISS

Korea Research Institute of Standards and Science, Korea, Republic of, APMP

LGC

Laboratory of the Government Chemist, United Kingdom, EURAMET

NIST

National Institute of Standards and Technology, United States, SIM

NMIJ AIST

National Metrology Institute of Japan, Japan, APMP

NMi-VSL

Nederlands Meetinstituut - Van Swinden Laboratorium (became VSL in 2009), Netherlands, EURAMET

NRC

National Research Council, Canada, SIM

PTB

Physikalisch-Technische Bundesanstalt, Germany, EURAMET

MEASURAND : Amount content of Cadmium in natural water 
NOMINAL VALUE : 83 nmol/kg

The key comparison reference value, xR, was calculated as the mean of the participant results;  xR = 83.49 nmol/kg.
The uncertainty of the key comparison reference value was calculated as the standard uncertainty of the 9 results; uR = 0.83 nmol/kg.

The degree of equivalence of each laboratory with respect to the key comparison reference value is given by a pair of terms: Di = (xi - xR) and Ui, its expanded uncertainty (k = 2), both expressed in nmol/kg, Ui = 2(ui2 + uR2)1/2.

The degree of equivalence between two laboratories is given by a pair of terms:
Dij = xi - xj and Uij, its expanded uncertainty (k = 2), both expressed in nmol/kg,
Uij = 2(ui2 + uj2)1/2 .

MEASURAND : Amount content of Lead in natural water
NOMINAL VALUE : 63 nmol/kg

The key comparison reference value, xR, was calculated as the mean of the participant results, excluding the PTB result; xR = 62.79 nmol/kg.
The uncertainty of the key comparison reference value was calculated as the standard uncertainty of the 8 results; uR = 1.33 nmol/kg.

The degree of equivalence of each laboratory with respect to the key comparison reference value is given by a pair of terms: Di = (xi - xR) and Ui, its expanded uncertainty (k = 2), both expressed in nmol/kg, Ui = 2(ui2 + uR2)1/2.

The degree of equivalence between two laboratories is given by a pair of terms:
Dij = xi - xj and Uij, its expanded uncertainty (k = 2), both expressed in nmol/kg,
Uij = 2(ui2 + uj2)1/2 .

MEASURAND : Amount content of Cadmium in natural water
NOMINAL VALUE : 83 nmol/kg

xi : result of measurement carried out by laboratory i
ui : combined standard uncertainty (k = 1) of xi

 Lab i xi
/ (nmol/kg)
ui
/ (nmol/kg)
Date of measurement
 IRMM 83.40 1.25 98-08
 KRISS 82.90 0.63 98-08
 LGC 83.07 0.30 98-09
 BNM-LNE 84.80 1.95 98-09
 NIMC* 84.60 1.00 98-09
 NIST 82.38 0.11 98-12
 NMi-VSL 83.90 0.90 98-08
 NRC 83.70 1.10 98-09
 PTB 82.70 1.10 98-09

*At the time of the comparison NMIJ (National Metrology Institute of Japan) was designated as NIMC (National Institute of Material and Chemical research).

Graph of individual measurements

MEASURAND : Amount content of Lead in natural water
NOMINAL VALUE : 63 nmol/kg

xi : result of measurement carried out by laboratory i
ui : combined standard uncertainty (k = 1) of xi

 Lab i xi
/ (nmol/kg)
ui
/ (nmol/kg)
Date of measurement
 IRMM 62.70 0.26 98-08
 KRISS 62.30 0.45 98-08
 LGC 62.34 0.62 98-09
 BNM-LNE 65.90 1.35 98-09
 NIMC* 62.21 0.30 98-09
 NIST 62.84 0.15 98-12
 NMi-VSL 61.40 1.10 98-08
 NRC 62.60 0.75 98-09
 PTB 61.00 0.45 98-09

*At the time of the comparison NMIJ (National Metrology Institute of Japan) was designated as NIMC (National Institute of Material and Chemical research).

                                      Graph of individual measurements