CCQM-K173 and CCQM-K173.1

MEASURAND   Amount content of bases expressed as sodium carbonate (Na2CO3)

NOMINAL VALUE 10 mol/kg

Degrees of equivalence represented by Di = (xI - xR) and its expanded uncertainty Ui at a 95 % level of confidence (k = 2), both expressed in mol/kg.

Amount content of Na2CO3
Di / (mol/kg)
Participating institutes

CCQM-K173 and CCQM-K173.1

MEASURAND   Amount content of bases expressed as sodium carbonate (Na2CO3)

NOMINAL VALUE 10 mol/kg

Degrees of equivalence represented by Di = (xI - xR) and its expanded uncertainty Ui at a 95 % level of confidence (k = 2), both expressed in mol/kg.

LABi Di Uneg,i Upos,i
mol/kg
mol/kg
mol/kg
INMETRO -0.0068 0.0259
SE "Ukrmetrteststandard" -0.0051 0.0172
NMIJ -0.0016 0.0027
SMU -0.0014 0.0024
NIM -0.0012 0.0025
UNIIM 0.0012 0.0028
CENAM 0.0019 0.0026
BAM 0.0019 0.0041
CMI 0.0060 0.0068
KRISS -0.0027 0.0032
Participating institutes
CCQM-K173
CCQM-K173.1
Comparison
Comparison close
CC comparison
Linked comparison
CCQM-K173
Metrology area, Sub-field Chemistry and Biology, Electrochemistry
Description Assay of sodium carbonate
Time of measurements 2021
Status Approved for equivalence
Final Reports of the comparisons
References

CCQM-K173 Technical protocol

Measurand Amount content
Transfer device Solid sodium carbonate samples
Comparison type Key Comparison
Consultative Committee CCQM (Consultative Committee for Amount of Substance)
Conducted by CCQM (Consultative Committee for Amount of Substance)
Comments Results published on 25 January 2023
Pilot institute NIM
National Institute of Metrology
China
Contact person Wu Bing

86-010-64524751
Additional
First Name Last Name
wwww@ww.www +356719836 Institute 1 Institute 1 Khmelnitskiy
Pilot laboratory
NIM

National Institute of Metrology, China, APMP

BAM

Bundesanstalt für Materialforschung und -prüfung, Germany, EURAMET

CENAM

Centro Nacional de Metrologia, Mexico, SIM

CMI

Czech Metrology Institute, Czechia, EURAMET

INMETRO

Instituto Nacional de Metrologia, Qualidade e Tecnologia, Brazil, SIM

INTI

Instituto Nacional de Tecnologia Industrial, Argentina, SIM

NIST

National Institute of Standards and Technology, United States, SIM

NMIJ AIST

National Metrology Institute of Japan, Japan, APMP

SE "Ukrmetrteststandard"

State Enterprise "Ukrmetrteststandard", Ukraine, EURAMET

SMU

Slovensky Metrologicky Ustav, Slovakia, EURAMET

VNIIM

D.I. Mendeleyev Institute for Metrology, Rosstandart, Russian Federation, COOMET

CCQM-K173 and CCQM-K173.1

 

MEASURAND   Amount content of bases expressed as sodium carbonate (Na2CO3)

NOMINAL VALUE 10 mol/kg

The key comparison reference value xR and its associated standard uncertainty uR are computed from the median of the results of the participants, excluding CMI, INMETRO and SE "Ukrmetrteststandard" (See further detailed information in section 8.1 of the CCQM-K173 Final report.

         xR = 9.4320 mol/kg     uR = 0.00114 mol/kg

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR is given by a pair of terms, both expressed in mol/kg:

Di = (xi - xR) and its expanded uncertainty Ui at a 95 % level of confidence where Ui = 2 (ui 2 + uR2)1/2

 

Linking CCQM-K173.1 to CCQM-K173

SMU provides the link between the key CCQM-K173 and CCQM-K173.1, having participated in both comparisons. The linking process is described in Section 8 of the CCQM-K173.1 Final report.

CCQM-K173 and CCQM-K173.1

MEASURAND   Amount content of bases expressed as sodium carbonate (Na2CO3)

NOMINAL VALUE 10 mol/kg

 

xi   measurement value reported by laboratory iLabi

ui   standard uncertainty of xi

 

CCQM-K173

  Labi xi ui
    mol kg-1 mol kg-1
  INMETRO 9.4252 0.0129
  SE "Ukrmetrteststandard" 9.4269 0.0085
  NMIJ 9.43042 0.00068
  SMU 9.4306 0.00041
  NIM 9.43082 0.00051
  VNIIM 9.4332 0.00085
  CENAM 9.43386 0.00060
  BAM 9.4339 0.0017
  CMI 9.4380 0.0032

 

CCQM-K173.1

  Labi xi ui
    mol kg-1 mol kg-1
  SMU 9.4328 0.0005
  KRISS 9.4315 0.0010