CCQM-K96.2023

 

MEASURAND   Amount content of oxidants expressed as potassium dichromate

NOMINAL VALUE 3.4 mol/kg

 

Degrees of equivalence represented by Di = (xI - xR) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in mol/kg.

Amount content of oxidants as potassium dichromate
Di / (mol/kg)
Participating institutes

CCQM-K96.2023

 

MEASURAND   Amount content of oxidants expressed as potassium dichromate

NOMINAL VALUE 3.4 mol/kg

 

Degrees of equivalence represented by Di = (xI - xR) and its expanded uncertainty Ui at a 95 % level of confidence, both expressed in mol/kg.

LABi Di Uneg,i Upos,i
(mol/kg)
(mol/kg)
(mol/kg)
CENAM -0.00155 0.00044
INMETRO -0.00125 0.00048
KRISS 0.00034 0.00040
NIM -0.00010 0.00042
NMIJ 0.00015 0.00045
SMU 0.00010 0.00039
Participating institutes
CCQM-K96.2023
Comparison
Comparison close
CC comparison
Linked comparison
CCQM-K96.2023.1
Metrology area, Sub-field Chemistry and Biology, Electrochemistry
Description Assay of potassium dichromate
Time of measurements 2023 -
Status Report in progress, draft A
Measurand Amount content of oxidants expressed as potassium dichromate
Transfer device High purity potassium dichromate
Comparison type Key Comparison
Consultative Committee CCQM (Consultative Committee for Amount of Substance)
Conducted by CCQM (Consultative Committee for Amount of Substance)
Pilot institute KRISS
Korea Research Institute of Standards and Science
Korea, Republic of
Contact person Kyungmin Jo

82-42-868-5621
First Name Last Name
wwww@ww.www +356719836 Institute 1 Institute 1 Khmelnitskiy
Pilot laboratory
KRISS

Korea Research Institute of Standards and Science, Korea, Republic of, APMP

VNIIM

D.I. Mendeleyev Institute for Metrology, Rosstandart, Russian Federation, COOMET

CCQM-K96.2023

 

MEASURAND   Amount content of oxidants expressed as potassium dichromate

NOMINAL VALUE 3.4 mol/kg

 

The key comparison reference value xR and its associated standard uncertainty uR are calculated according to Section 8 of the CCQM-K96.2023 Final report, with respect to the median as best estimate using results from all participants.

 

        xR = 3.39872 mol/kg     uR = 0.00019 mol/kg

 

The degree of equivalence of laboratory i relative to the key comparison reference value xR is given by a pair of terms, both expressed in mol/kg:

Di = (xi - xR) and its expanded uncertainty Ui at a 95 % level of confidence where Ui = 2 ((1 - (2/m)ui2 + uR2))1/2 where m is the number of results contributing to the KCRV (see section 9 of the CCQM-K96.2023 Final report).

CCQM-K96.2023

 

MEASURAND   Amount content of oxidants expressed as potassium dichromate

NOMINAL VALUE 3.4 mol/kg

 

xi   result of measurement reported by laboratory iLab

ui   combined standard uncertainty of xi

kLabi  coverage factor reported by laboratory i,

ULabi   expanded uncertainty of xi at 95 % level of confidence where ULabikLabiu

  Labi xi ULabi kLabi
  mol/kg mol/kg  
  CENAM 3.397167 0.000307 2.1
  INMETRO 3.397473 0.003850 2.1
  KRISS 3.399055 0.000273 2.8
  NIM 3.398623 0.000242 2.0
  NMIJ 3.398872 0.000314 2.0
  SMU 3.398815 0.000129 2.0