MEASURAND: Mass fraction of Chromium in low alloy steel

Degrees of equivalence: Di = (xi - xR) and expanded uncertainty Ui (k = 2), both expressed in %

MEASURAND: Mass fraction of Manganese in low alloy steel

Degrees of equivalence: Di = (xi - xR) and expanded uncertainty Ui (k = 2), both expressed in %

MEASURAND : Mass fraction of Nickel in low alloy steel

Degrees of equivalence: Di = (xi - xR) and expanded uncertainty Ui (k = 2), both expressed in %

MEASURAND: Mass fraction of Molybdenum in low alloy steel

Degrees of equivalence: Di = (xi - xR) and expanded uncertainty Ui (k = 2), both expressed in %

MEASURAND : Mass fraction of Chromium in low alloy steel

The table below gives the degrees of equivalence for participant laboratory i.

Results are presented under A4 printable format in Summary Results (.PDF file).

MEASURAND : Mass fraction of Manganese in low alloy steel

The table below gives the degrees of equivalence for participant laboratory i.

Results are presented under A4 printable format in Summary Results (.PDF file).

MEASURAND : Mass fraction of Nickel in low alloy steel

The table below gives the degrees of equivalence for participant laboratory i.

Results are presented under A4 printable format in Summary Results (.PDF file).

MEASURAND : Mass fraction of Molybdenum in low alloy steel

The table below gives the degrees of equivalence for participant laboratory i.

Results are presented under A4 printable format in Summary Results (.PDF file).

Comparison
Comparison close
CC comparison
Linked comparison
CCQM-K33
Metrology area, Sub-field Chemistry and Biology, Inorganics
Description Minor elements in steel
Time of measurements 2003 - 2004
Status Approved for equivalence
Final Reports of the comparisons
Measurand Mass fraction of Cr, Ni, Mn and Mo in low alloy steel: levels in the range of 0.1% to 3%
Transfer device Bottles containing small chips of low alloy steel
Comparison type Key Comparison
Consultative Committee CCQM (Consultative Committee for Amount of Substance)
Conducted by CCQM (Consultative Committee for Amount of Substance)
Comments

Results published on 24 March 2006

Minor elements in low alloy steel

Pilot institute NMIJ AIST
National Metrology Institute of Japan
Japan
Contact person A. Hioki

+81 29 861 9341
Additional
First Name Last Name
wwww@ww.www +356719836 Institute 1 Institute 1 Khmelnitskiy
Pilot laboratory
NMIJ AIST

National Metrology Institute of Japan, Japan, APMP

BAM

Bundesanstalt für Materialforschung und -prüfung, Germany, EURAMET

CENAM

Centro Nacional de Metrologia, Mexico, SIM

CSIR-NML

Council for Scientific and Industrial Research, National Metrology Laboratory (became NMISA in 2007), South Africa, AFRIMETS

KRISS

Korea Research Institute of Standards and Science, Korea, Republic of, APMP

LGC

Laboratory of the Government Chemist, United Kingdom, EURAMET

NIST

National Institute of Standards and Technology, United States, SIM

SP

Technical Research Institute of Sweden from 2017 Research Institutes of Sweden AB, Sweden, EURAMET

VNIIM

D.I. Mendeleyev Institute for Metrology, Rosstandart, Russian Federation, COOMET

MEASURAND : Mass fraction of Chromium in low alloy steel

The key comparison reference value, xR, is calculated as the median of all participant results. Its expanded uncertainty (k = 2), UR, is computed as explained on page 11 of the Final Report

xR = 0.5091 %,  UR = 0.0030 %

The degree of equivalence of laboratory i relative to the key comparison reference value is given by a pair of terms, both expressed in %:
Di = (xi - xR) and its expanded uncertainty Ui (k = 2), Ui = 2(ui2 + uR2)1/2.

The degrees of equivalence between pair of laboratories have not been computed for this key comparison.

MEASURAND : Mass fraction of Manganese in low alloy steel

The key comparison reference value, xR, is calculated as the median of all participant results. Its expanded uncertainty (k = 2), UR, is computed as explained on page 11 of the Final Report.

xR = 0.5063 %, UR = 0.0016 %

The degree of equivalence of laboratory i relative to the key comparison reference value is given by a pair of terms, both expressed in %:
Di = (xi - xR) and its expanded uncertainty Ui (k = 2), Ui = 2(ui2 + uR2)1/2.

The degrees of equivalence between pair of laboratories have not been computed for this key comparison.

MEASURAND : Mass fraction of Nickel in low alloy steel

The key comparison reference value, xR, is calculated as the median of the participant results with the exclusion of CENAM and NIST results. Its expanded uncertainty
(k = 2), UR, is computed as explained on page 11 of the Final Report.

xR = 2.5490 %, UR = 0.0123 %

The degree of equivalence of laboratory i relative to the key comparison reference value is given by a pair of terms, both expressed in %:
Di = (xi - xR) and its expanded uncertainty Ui (k = 2), Ui = 2(ui2 + uR2)1/2.

The degrees of equivalence between pair of laboratories have not been computed for this key comparison.

MEASURAND : Mass fraction of Molybdenum in low alloy steel

The key comparison reference value, xR, is calculated as the median of all participant results. Its expanded uncertainty (k = 2), UR, is computed as explained on page 11 of the Final Report.

xR = 1.0393 %, UR = 0.0058 %

The degree of equivalence of laboratory i relative to the key comparison reference value is given by a pair of terms, both expressed in %:
Di = (xi - xR) and its expanded uncertainty Ui (k = 2), Ui = 2(ui2 + uR2)1/2.

The degrees of equivalence between pair of laboratories have not been computed for this key comparison.

MEASURAND : Mass fraction of Chromium in low alloy steel

xi : result of measurement carried out by laboratory i
ULabi : expanded uncertainty of xi
kLabi : coverage factor, ULabi = kLabi ui , with ui the combined standard uncertainty of xi

 Lab i xi
/ %
ULabi
/ %
kLabi
 BAM 0.5115 0.0018 2
 CENAM

0.5130

0.0127

2.2

 CSIR-NML

0.5114

0.0122

2

 KRISS

0.5068

0.0067

2.06

 LGC 0.5056 0.0065 2
 NIST 0.5060 0.0042 2
 NMIJ 0.5118 0.0021 2
 VNIIM 0.506 0.018 2

MEASURAND : Mass fraction of Manganese in low alloy steel

xi : result of measurement carried out by laboratory i
ULabi : expanded uncertainty of xi
kLabi : coverage factor, ULabi = kLabi ui , with ui the combined standard uncertainty of xi

 Lab i xi
/ %
ULabi
/ %
kLabi
 BAM 0.511 0.007 2
 CENAM

0.5017

0.0112

2.11

 CSIR-NML

0.5067

0.0060

2

 KRISS

0.5072

0.0011

2.04

 LGC 0.5058 0.0048 2
 NIST 0.5040 0.0077 2
 NMIJ 0.5049 0.0043 2
 VNIIM 0.508 0.018 2

MEASURAND : Mass fraction of Nickel in low alloy steel

xi : result of measurement carried out by laboratory i
ULabi : expanded uncertainty of xi
kLabi : coverage factor, ULabi = kLabi ui , with ui the combined standard uncertainty of xi

 Lab i xi
/ %
ULabi
/ %
kLabi
 BAM 2.5497 0.0429 2
 CENAM(1)

2.6502

0.1028

2.36

 CSIR-NML

2.560

0.058

2

 KRISS

2.524

0.022

1.97

 LGC

2.549

0.047

2

 NIST(2)

2.479

0.021

2

 NMIJ 2.5385 0.0072 2
 SP 2.536 0.021 2
 VNIIM 2.58 0.09 2

(1) Result from CENAM as originally submitted and used for calculation of equivalence.
After circulation of the Draft A Report, CENAM reported a problem of measurement outliers. The correct result is as follows: xCENAM = 2.6032 %, UCENAM = 0.0656 % (k = 2.45).
(2) Result from NIST as originally submitted and used for calculation of equivalence.
After disclosure of all results from participants, NIST discovered a calibration error. The correct result is as follows: xNIST = 2.533 %, UNIST = 0.029 % (k = 2).

MEASURAND : Mass fraction of Molybdenum in low alloy steel

xi : result of measurement carried out by laboratory i
ULab i : expanded uncertainty of xi
kLab i : coverage factor, ULab i = kLabi ui , with ui the combined standard uncertainty of xi

 Lab i xi
/ %
ULabi
/ %
kLabi
 BAM 1.0475 0.0136 2
 CENAM

1.0325

0.0257

2.2

 CSIR-NML

1.052

0.023

2

 KRISS

1.0353

0.0034

2.04

 LGC 1.035 0.014 2
 NIST 1.0371 0.0056 2
 NMIJ 1.0415 0.0080 2
 VNIIM 1.05 0.039 2